Gouache is a water-based paint with the same binder as watercolour, but with more pigment and an addition of white or chalk. That single difference in the recipe changes everything: gouache does not glow through, it covers whatever lies beneath it.
In watercolour the light comes from the white of the paper, so the brightest areas have to be planned and left untouched from the first stroke. Gouache works the other way round: pale colour goes over dark at the end. That is why it can be used on coloured or grey paper, with the highlights added once it is clear where they are needed.
Gouache dries to a matt, even surface with no streaks and no sheen, it renders flat areas of colour faithfully and it reproduces well. For centuries it therefore accompanied drawings of plants and birds prepared for printing, and it still suits work where clean, uniform colour and a firm outline matter most.
The two paints combine happily on one sheet: transparent watercolour builds the background and the shadow, while a few touches of gouache bring back the light that watercolour has no way of recovering. Only the proportion needs watching, because gouache used everywhere takes away the transparency that is the greatest asset of paper.
Works on paper that rely on exactly that transparency are in the watercolours gallery.